Possible. Depends on how it's done really
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Pokécharms
Ry_Burst
Mechanist Gamma
What I'm thinking is I'd be the storyteller, and I'd assign everyone their roles through an RNG generator and tell them what their roles are through convo. The separate convos would also be where I ask who wants to do what and carry messages across.
Ry_Burst
Interesting. I'm in
Il Fantasma
I freaking love Mafia, man! I've played it before with my IRL friends, and it's so much fun! Count me in, for sure! 
Yaspen
Alright, I'm in!
Grand Master Koop
yeah sure
Mechanist Gamma
I think we've got enough people to at least get the convo made. I'll do it now.
Grand Master Koop
why not also call @Stormursa
Stormursa
Id be up for it
Yaspen
This is gonna be awesome!
Jagson
Seems interesting. I'm in.
Palusokudo
You summoned me? Oh yeah that's sounds cool. 